Catalytic Ethenylation Reaction of Phenol Using SnCl4
Organic Letters2000Vol. 3(2), pp. 241–242
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Abstract
Ethenylation reaction of phenol with silylethyne at the o-position is catalyzed by the SnCl4−BuLi reagent. While turn over numbers (TONs) in the reactions of m- or p-substituted phenols are 3 to 4, those for o-substituted phenols are 8 to 9.
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