An Expeditious Approach toward the Total Synthesis of CP-263,114
Organic Letters2001Vol. 3(16), pp. 2435–2438
Citations Over TimeTop 10% of 2001 papers
Abstract
[reaction: see text] Assembly of the carbocyclic core of CP-263,114 has been accomplished efficiently and in high yield. Key steps include a phenolic oxidation/intramolecular Diels-Alder sequence, tandem radical cyclization, and the late-stage fragmentation of a densely functionalized isotwistane skeleton.
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