N-Methylated 5-Alkenyloxazolium Salt Transformations
Organic Letters2001Vol. 3(15), pp. 2301–2303
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David Wenkert, Tse-Fang Chen, Kishore Ramachandran, Lucy Valasinas, Weng Ling-ling, Andrew T. McPhail
Abstract
[reaction: see text] In the course of natural product synthetic studies, 5-(4-pentenyl)oxazole and 5-(5-hexenyl)oxazole were N-methylated. The initial N-methylated 5-alkenyloxazolium salt adducts were found to be only intermediates and were ultimately transformed into hydroindole and hydroisoquinoline compounds, respectively.
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