Studies toward the Total Synthesis of Popolohuanone E: Enantioselective Synthesis of 8-O-MethylpopolohuanoneE
Organic Letters2001Vol. 3(17), pp. 2701–2704
Citations Over TimeTop 12% of 2001 papers
Tadashi Katoh, Mari Nakatani, Shoji Shikita, Ruriko Sampe, Akihiro Ishiwata, Osamu Ohmori, Masahiko Nakamura, Shiro Terashima
Abstract
[structure: see text]. 8-O-methylpopolohuanone E (2) was synthesized in a highly convergent manner starting from the cis-fused decalin derivative accessible from the (-)-Wieland-Miescher ketone analogue. The synthetic method features a biogenetic-type annulation of the phenolic and quinone segments to regioselectively construct the central tricyclic ring system as the key step.
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