Palladium-Catalyzed Stereocontrolled Vinylation of Azoles and Phenothiazine
Organic Letters2002Vol. 4(4), pp. 623–626
Citations Over TimeTop 10% of 2002 papers
Artem Y. Lebedev, Vyatcheslav V. Izmer, Denis N. Kazyul'kin, I. P. Beletskaya, Alexander Z. Voskoboynikov
Abstract
[reaction: see text] Vinylation of various azoles (pyrrole, indole, carbazole, and their derivatives) and phenothiazine with vinyl bromides catalyzed by palladium-phosphine complexes results in the respective N-vinylazoles in 30-99% yields. This reaction with cis- and trans-beta-bromostyrenes is stereospecific giving the respective products with full retention of configuration.
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