Control of Enantioselectivity in the Photochemical Conversion of α-Oxoamides into β-Lactam Derivatives
Organic Letters2002Vol. 4(9), pp. 1443–1446
Citations Over TimeTop 10% of 2002 papers
Abstract
[reaction: see text]. Several approaches to asymmetric induction in the alpha-oxoamide (1) to beta-lactam (2) photorearrangement are described. Best results are obtained via irradiation of ionic and covalent chiral auxiliary-containing reactants in the crystalline state and in the interior supercages of zeolites.
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