Highly Chemoselective Rhodium-Catalyzed Methylenation of Fluorine-Containing Ketones
Organic Letters2002Vol. 4(10), pp. 1671–1674
Citations Over TimeTop 10% of 2002 papers
Abstract
[reaction: see text] The rhodium(I)-catalyzed methylenation of functionalized fluorinated ketones using trimethylsilyldiazomethane proceeds to give the corresponding fluoromethylalkenes in good yields (61-90%). Remarkable chemoselectivity was observed for the synthesis of keto-substituted organofluorine alkenes.
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