Efficient Ligandless Palladium-Catalyzed Suzuki Reactions of Potassium Aryltrifluoroborates
Organic Letters2002Vol. 4(11), pp. 1867–1870
Citations Over TimeTop 10% of 2002 papers
Abstract
[reaction: see text] The ligandless palladium-catalyzed Suzuki cross-coupling reaction of potassium aryl- and heteroaryltrifluoroborates with aryl- or heteroaryl halides or triflates proceeds readily with very good yields. The cross coupling can be effected in methanol or water, in the open air, using Pd(OAc)(2) as a catalyst in the presence of K(2)CO(3). A variety of functional groups are tolerated.
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