Ruthenium-Catalyzed Hydrosilylation of 1-Alkynes with Novel Regioselectivity
Organic Letters2002Vol. 4(17), pp. 2825–2827
Citations Over TimeTop 10% of 2002 papers
Abstract
[reaction: see text] A ruthenium catalyst precursor bearing a bulky and electron-donating pentamethylcyclopentadienyl (Cp) ligand, typically CpRuH3(PPh3), mediates hydrosilylation of several 1-alkynes with novel regioselectivity to give preferentially 2-silyl-1-alkenes.
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