Highly Enantioselective Hydrogenation of Enol Acetates Catalyzed by Ru−TunaPhos Complexes
Organic Letters2002Vol. 4(25), pp. 4495–4497
Citations Over TimeTop 10% of 2002 papers
Abstract
[reaction: see text] The chiral disphosphines with tunable dihedral angles (TunaPhos) have been used for asymmetric hydrogenation of enol acetates and dihedral-angle-dependent enantioselectivities were observed. C2-TunaPhos has been proved to be effective for Ru-catalyzed asymmetric hydrogenation of electron-deficient and other enol acetates.
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