Aldol- and Mannich-Type Reactions via in Situ Olefin Migration in Ionic Liquid
Organic Letters2003Vol. 5(5), pp. 657–660
Citations Over TimeTop 10% of 2003 papers
Abstract
An aldol-type and a Mannich-type reaction via the cross-coupling of aldehydes and imines with allylic alcohols catalyzed by RuCl(2)(PPh(3))(3) was developed with ionic liquid as the solvent. The solvent/catalyst system could be reused for at least five times with no loss of reactivity.
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