Successive Iodine−Magnesium or −Copper Exchange Reactions for the Selective Functionalization of Polyhalogenated Aromatics
Organic Letters2003Vol. 5(8), pp. 1229–1231
Citations Over TimeTop 10% of 2003 papers
Abstract
[reaction: see text] The presence of an electron-withdrawing group or chelating group was found to direct the halogen-copper and halogen-magnesium exchange with various di- or trihalogenated aromatics. Starting with a triiodobenzoate derivative, a range of tetraacylated benzenes could be prepared and used for a short synthesis of benzodiazines.
Related Papers
- → Surface functionalization of microporous carbon fibers by vapor phase methods for CO2 capture(2023)3 cited
- → Selective external surface functionalization of large-pore silica materials capable of protein loading(2016)24 cited
- → Thermal Functionalization of GaN Surfaces with 1-Alkenes(2013)13 cited
- → 733. Mixtures of halogens and halogen polyfluorides as effective sources of the halogen monofluorides in reactions with fluoro-olefins(1961)56 cited
- → 4. Introduction of Fluorine by Halogen Fluorides : 4.3. Halofluorination with Stoichiometric Equivalents of Halogen Fluorides (Positive Halogen and HF or Its Salts)(1998)