Generation and Intramolecular Reactivity of Acyl Radicals from Alkynylthiol Esters under Reducing Tin-Free Conditions
Organic Letters2003Vol. 5(8), pp. 1313–1316
Citations Over TimeTop 11% of 2003 papers
Luisa Benati, G. Calestani, Rino Leardini, Matteo Minozzi, Daniele Nanni, Piero Spagnolo, Samantha Strazzari
Abstract
[reaction: see text] The radical chain reaction of benzenethiol with alkynylthiol esters provides a new, valuable protocol for the tin-free generation of acyl radicals that arise from intramolecular substitution at sulfur by the initial sulfanylvinyl radicals.
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