First Heck Reaction with Arenediazonium Cations with Recovery of Pd-Triolefinic Macrocyclic Catalyst
Organic Letters2003Vol. 5(9), pp. 1559–1561
Citations Over TimeTop 10% of 2003 papers
Abstract
The air- and moisture-stable phosphine-free palladium(0) complex 1 is a highly active and recoverable catalyst for Heck olefination of aryl diazonium tetrafluoroborates. The reactions were performed under aerobic conditions at room temperature to give the coupling products in excellent yields. [reaction: see text]
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