First Zipper-Featured Molecular Duplexes Driven by Cooperative Donor−Acceptor Interaction
Organic Letters2003Vol. 5(11), pp. 1955–1958
Citations Over TimeTop 10% of 2003 papers
Abstract
[structure: see text] The first class of zipper-shaped artificial duplexes, which are driven by multiple donor-acceptor interactions between electron-rich 1,5-dioxynaphthalene or 1,4-dioxybenzene and electron-deficient pyromellitic dimide units, have been studied in organic media by (1)H NMR, UV-vis, and vapor pressure osmometry. (1)H NMR binding investigations reveal substantial cooperativity of the donor-acceptor interaction in the duplexes.
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