A New Cationic, Chiral Catalyst for Highly Enantioselective Diels−Alder Reactions
Organic Letters2003Vol. 5(14), pp. 2465–2467
Citations Over TimeTop 11% of 2003 papers
Abstract
[reaction: see text] The Diels-Alder reaction of cyclopentadiene and 2-methacrolein is catalyzed by a chiral Lewis acid to form the exo adduct in 96% yield and 96% ee.
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