Synthesis of Substituted P-Stereogenic Vinylphosphine Oxides by Olefin Cross-Metathesis
Organic Letters2003Vol. 5(18), pp. 3217–3220
Citations Over TimeTop 10% of 2003 papers
Abstract
[reaction: see text] Substituted vinylphosphine oxides have been prepared in good yield and exclusive (E)-olefin selectivity via olefin cross-metathesis using Grubbs and Hoveyda-type ruthenium catalysts. In addition, metathesis of chiral vinylphosphine oxides proceeds without racemization of the phosphorus chirality center, providing easy access to functionalized chiral nonracemic (E)-alkenylphosphine oxides.
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