R3Al−R‘3SiOTf: Novel and Powerful Reagent System for Stereospecific Alkylation−Silylation Reactions of Epoxides
Organic Letters2003Vol. 5(18), pp. 3265–3268
Citations Over TimeTop 16% of 2003 papers
Abstract
[reaction: see text] A novel and powerful reagent system R(3)Al-R'(3)SiOTf for the one-pot alkylation-silylation reaction of epoxides was discovered, and the reactions of various epoxides with the new reagent system have been demonstrated to occur stereospecifically giving rise to the corresponding alkylation-silylation products in excellent yields.
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