First Cross-Coupling Reactions on Tetrazines
Organic Letters2003Vol. 5(19), pp. 3495–3497
Citations Over TimeTop 21% of 2003 papers
Abstract
[reaction: see text] A series of substituted chlorotetrazines were reacted with different terminal alkynes under Sonogashira or Negishi coupling conditions to furnish alkynyl-tetrazines in good to moderate yield. The electron-donating properties of the substituent on the tetrazine core were found to have a significant influence on the success of the reaction. These results constitute the first cross-coupling reactions on tetrazines.
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