Novel Functionalized Trisubstituted Allylboronates via Hosomi−Miyaura Borylation of Functionalized Allyl Acetates
Organic Letters2004Vol. 6(4), pp. 481–484
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P. Veeraraghavan Ramachandran, Debarshi Pratihar, Debanjan Biswas, Amit Srivastava, M. Venkat Ram Reddy
Abstract
[reaction: see text] A series of novel functionalized achiral and chiral allylboronates have been synthesized via the nucleophilic addition of boronates on allyl acetates derived via vinylalumination or Baylis-Hillman reaction of aldehydes. These reagents, upon allylboration with aldehydes, furnish beta-substituted-alpha-methylene-gamma-butyrolactones stereoselectively.
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