Synthesis and Self-Assembly of Functionalized Donor−σ−Acceptor Molecules
Organic Letters2005Vol. 7(3), pp. 443–446
Citations Over TimeTop 16% of 2005 papers
Abstract
[structure: see text] 3,5,7-Tris(arylmethyl)-1-aza-adamantanetrione donor-sigma-acceptor compounds have been synthesized in four steps. Computational and (1)H NMR analyses rationalize the solubility, gelation, and conformational properties of the C3-symmetric molecules toward employing sigma-coupled donor-acceptor interactions in molecular self-assembly.
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