Water Enables Direct Use of Allyl Alcohol for Tsuji−Trost Reaction without Activators
Organic Letters2004Vol. 6(22), pp. 4085–4088
Citations Over TimeTop 10% of 2004 papers
Abstract
[reaction: see text] An aqueous biphasic reaction system enables the direct use of allyl alcohol in the Tsuji-Trost reaction without the help of any activating reagents for allyl alcohol. The reaction conditions are neutral to basic, allowing the use of amines as the nucleophile. Theoretical calculations have elucidated the importance of hydration of the hydroxy group for the smooth generation of pi-allylpalladium species.
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