Syntheses of the C(1−6) and C(19−24) Fragments of Lituarines A, B, and C
Organic Letters2004Vol. 6(21), pp. 3857–3859
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Abstract
[structure: see text] Lituarines A-C are marine natural products comprising a tricyclic spiroacetal bridged at C(8) and C(18) by a functionalized ester linkage conceptually obtained from a C(19-24) alcohol and a C(1-6) carboxylic acid whose oxidation level varies at C(4) and C(5). Stereoselective routes are described to compounds 26 and 27, fully functionalized ester fragments of lituarine A and lituarines B and C, respectively.
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