Palladium-Catalyzed Decarboxylation and Decarbonylation under Hydrothermal Conditions: Decarboxylative Deuteration
Organic Letters2004Vol. 6(12), pp. 2071–2073
Citations Over TimeTop 10% of 2004 papers
Abstract
[reaction: see text] Decarboxylation of free carboxylic acid was performed by Pd/C catalyst under hydrothermal water (250 degrees C/4 MPa). Under the hydrothermal conditions of deuterium oxide, decarbonylative deuteration was observed to give fully deuterated hydrocarbons from carboxylic acids or aldehydes.
Related Papers
- → Theoretical investigation of the decarboxylation and decarbonylation mechanism of propanoic acid over a Ru(0 0 0 1) model surface(2015)53 cited
- → Forging C–S Bonds through Nickel-Catalyzed Aryl Anhydrides with Thiophenols: Decarbonylation or Decarbonylation Accompanied by Decarboxylation(2019)25 cited
- → Palladium‐Catalyzed Decarboxylation and Decarbonylation under Hydrothermal Conditions: Decarboxylative Deuteration.(2004)6 cited
- → Understanding the mechanism of thermal decomposition of benzoylformic acid(2023)2 cited
- Theoretical Studies on Formation Mechanism of CO and CO_2 in Pyrolysis of Lignin(2015)