ipso-Nitration of Arylboronic Acids with Chlorotrimethylsilane−Nitrate Salts
Organic Letters2004Vol. 6(13), pp. 2205–2207
Citations Over TimeTop 12% of 2004 papers
G. K. Surya Prakash, Chiradeep Panja, Thomas Mathew, Vijayalakshmi Surampudi, Nicos A. Petasis, George A. Olah
Abstract
[reaction: see text] A mixture of nitrate salt and chlorotrimethylsilane is found to be an efficient regioselective nitrating agent for the ipso-nitration of arylboronic acids to produce the corresponding nitroarenes in moderate to excellent yields. High selectivity, simplicity, and convenience are the key features of the reaction.
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