B(C6F5)3-Catalyzed Allylation of Propargyl Acetates with Allylsilanes
Organic Letters2004Vol. 6(12), pp. 1999–2001
Citations Over TimeTop 10% of 2004 papers
Abstract
[reaction: see text] An efficient method for the B(C(6)F(5))(3)-catalyzed allylation of secondary propargylic alcohol derivatives with allylsilanes has been developed. This method allows for the facile synthesis of a variety of 1,5-enynes in good to high yields with a number of functionalities, such as nitro, chloro, ester, and boronic ester, being tolerated under the reaction conditions.
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