Nickel-Catalyzed Addition of P(O)−H Bonds to Propargyl Alcohols: One-Pot Generation of Phosphinoyl 1,3-Butadienes
Organic Letters2005Vol. 7(14), pp. 2909–2911
Citations Over TimeTop 17% of 2005 papers
Abstract
[reaction: see text] Diphenylphosphine oxide and related P(O)H compounds react with propargyl alcohols at room temperature in the presence of a catalytic amount of Ni(0) complex and Ph(2)P(O)OH to produce high yields of phosphinoyl 1,3-dienes though an efficient in situ dehydration process.
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