Enhanced Small-Molecule Assembly through Directional Intramolecular Forces
Organic Letters2005Vol. 7(20), pp. 4471–4474
Citations Over TimeTop 16% of 2005 papers
Abstract
[reaction: see text] Directional intramolecular interactions play a critical role in the self-assembly of donor-sigma-acceptor molecules in solution. Amide functions on the periphery of the tricyclic core stabilize a C3-symmetric monomer conformation by intramolecular hydrogen bonding and dipole-dipole interactions. The molecules are effective organogelators and show long-range ordering in the bulk.
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