Meso-Structure Formation for Enhanced Organic Photovoltaic Cells
Organic Letters2005Vol. 7(26), pp. 5749–5752
Citations Over TimeTop 1% of 2005 papers
M. Reyes‐Reyes, Kyungkon Kim, James Dewald, R. López‐Sandoval, Aditya Avadhanula, Seamus A. Curran, David Carroll
Abstract
[reaction: see text] Formation of a controlled fullerene mesophase within an organic host system has enabled us to create high-power conversion efficiency photovoltaics. This mesophase is formed using thermal gradients that provide a fluidic mobility of the fullerenes allowing for greater dispersion of nanocrystalline 1-(3-methoxycarbonyl)propyl-1-phenyl-(6,6)C61 (PCBM) within regioregular poly(3-hexylthiophene) (P3HT). From this reorganization of the component materials in the matrix the overall efficiency of the system jumps dramatically from the roughly 2.4% to 5.2%.
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