Intramolecular Alkyne Hydroalkoxylation and Hydroamination Catalyzed by Iridium Hydrides
Organic Letters2005Vol. 7(24), pp. 5437–5440
Citations Over TimeTop 10% of 2005 papers
Abstract
[reaction: see text] Iridium(III) hydrides prove to be air-stable active catalysts for intramolecular hydroalkoxylation and hydroamination of internal alkynes with proximate nucleophiles. The cyclization follows highly selective 6-endo-dig regiochemistry when regioselectivity is an issue.
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