Palladium-Catalyzed Enantioselective Conjugate Addition of Arylboronic Acids
Organic Letters2005Vol. 7(23), pp. 5309–5312
Citations Over TimeTop 10% of 2005 papers
Abstract
[reaction: see text] The first asymmetric palladium-catalyzed conjugate addition of arylboronic acids to alpha,beta-unsaturated aldehydes, ketones, and esters is described. For cyclic substrates, excellent chemo-, regio-, and enantioselectivities are achieved when a Pd(O2CCF3)2/DuPHOS catalyst is applied.
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