Cyanosporasides A and B, Chloro- and Cyano-cyclopenta[ a ]indene Glycosides from the Marine Actinomycete “ Salinispora pacifica ”
Organic Letters2006Vol. 8(6), pp. 1021–1024
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Abstract
[structure: see text] Two structurally novel cyclopenta[a]indene glycosides, cyanosporasides A and B (1 and 2) have been isolated from the culture broth of a new species of the obligate marine actinomycete genus Salinispora. The structures and absolute stereochemistries of these compounds were determined by spectral and chemical methods. The cyanosporasides possess a new 3-keto-pyranohexose sugar as well as a cyano- and chloro-substituted cyclopenta[a]indene ring system. The cyanosporasides are proposed to be cyclization products of an enediyne precursor.
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