Enantioselective Total Synthesis of Convolutamydines B and E
Organic Letters2006Vol. 8(4), pp. 677–679
Citations Over TimeTop 10% of 2006 papers
Abstract
[reaction: see text] The first enantioselective total synthesis of convolutamydines B and E has been achieved using our vinylogous Mukaiyama aldol reaction. The synthesis features highly diastereoselective vinylogous Mukaiyama aldol reaction with isatin instead of aldehydes to construct a chiral center of convolutamydines. Additionally, the absolute configuration of natural convolutamydine B has been determined as R by its CD spectrum.
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