Versatile and Practical Chiral Shift Reagent with Hydrogen-Bond Donor/Acceptor Sites in a Macrocyclic Cavity
Organic Letters2006Vol. 8(17), pp. 3773–3775
Citations Over TimeTop 11% of 2006 papers
Abstract
[structure: see text] Bifunctional macrocycle 1 with C2 symmetry was newly synthesized. NMR studies demonstrated that receptor 1 functions as a chiral shift reagent (solvating agent) that is highly effective for a wide range of chiral compounds having a carboxylic acid, oxazolidinone, lactone, alcohol, sulfoxide, sulfoximine, isocyanate, or epoxide functionality. Binding constants were determined to investigate the binding behavior of 1.
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