A New Entry to Polycyclic Indole Skeletons via Palladium-Catalyzed Intramolecular Heteroannulation
Organic Letters2006Vol. 8(16), pp. 3573–3575
Citations Over TimeTop 10% of 2006 papers
Jianxiu Liu, Ming Shen, Yongda Zhang, Guisheng Li, Ahmad Khodabocus, Sonia Rodrı́guez, Bo Qu, Vittorio Farina, Chris H. Senanayake, Bruce Z. Lu
Abstract
[reaction: see text] A one-step method was developed for elaboration of a variety of polycyclic indole skeletons via a novel palladium-catalyzed intramolecular indolization of 2-chloroanilines bearing tethered acetylenes. This novel intramolecular indolization method unveils an unusual syn amidopalladation pathway of a tethered alkyne.
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