Generation of Aza-ortho-xylylenes via Ring Opening of 2-(2-Acylaminophenyl)aziridines: Application in the Construction of the Communesin Ring System
Organic Letters2006Vol. 8(18), pp. 3995–3998
Citations Over TimeTop 10% of 2006 papers
Abstract
A new protocol for generating aza-ortho-xylylenes via acid-catalyzed or fluoride-promoted ring opening of 2-(2-acylaminophenyl)aziridines is described. This methodology has been exploited in the rapid construction of a hexacyclic substructure of communesin B.
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