Benzo[a]acecorannulene: Surprising Formation of a New Bowl-Shaped Aromatic Hydrocarbon from an Attempted Synthesis of 1,2-Diazadibenzo[d,m]corannulene
Organic Letters2006Vol. 8(23), pp. 5195–5198
Citations Over TimeTop 15% of 2006 papers
Vikki M. Tsefrikas, Steve Arns, Patrick M. Merner, C. Chad Warford, Bradley L. Merner, Lawrence T. Scott, Graham J. Bodwell
Abstract
Flash vacuum pyrolysis of 7,10-bis(2-bromophenyl)acenaphtho[1,2-d]pyridazine (C26H14Br2N2) has resulted in a surprising transformation, including dinitrogen loss, to give benzo[a]acecorannulene, a novel C26H12 bowl-shaped fullerene fragment.
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