Synthesis of 2-epi-Amphidinolide E: An Unexpected and Highly Selective C(2) Inversion during an Esterification Reaction
Organic Letters2006Vol. 9(2), pp. 307–310
Citations Over TimeTop 11% of 2006 papers
Abstract
A synthesis of 2-epi-amphidinolide E (1) has been accomplished via an unexpected and highly diastereoselective C(2) stereochemical inversion during the modified Yamaguchi esterification of alcohol 4b and Fe(CO)3-complexed dienoic acid 7. [reaction: see text].
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