Divergent Pathways in the Reaction of Fischer Carbenes and Palladium
Organic Letters2007Vol. 9(9), pp. 1757–1759
Citations Over TimeTop 10% of 2007 papers
María P. López‐Alberca, María J. Mancheño, Israel Fernández, Mar Gómez‐Gallego, Miguel Á. Sierra, Rosario Torres
Abstract
[reaction: see text] The Pd-catalyzed reaction of beta-arylaminochromium(0) carbene complexes produces by transmetalation the first isolated and X-ray structurally characterized bis-Pd(II) carbene complex, as well as other alternative reaction pathways, such as the oxidative addition-transmetalation sequence, not seen before in this chemistry.
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