Diastereomeric Recognition of Chiral Foldamer Receptors for Chiral Glucoses
Organic Letters2007Vol. 9(9), pp. 1797–1800
Citations Over TimeTop 10% of 2007 papers
Abstract
[reaction: see text] Three chiral aromatic hydrazide foldamers have been designed and synthesized, in which two R- or S-proline units were incorporated at the terminals of their backbones. The 1H NMR, circular dichroism (CD), and fluorescent experiments and molecular dynamics simulations revealed that the foldamers adopted a chiral helical conformation and complexed alkylated glucoses in chloroform with a good diastereomeric selectivity.
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