Simple Preparation of Diamondoid 1,3-Dienes via Oxetane Ring Opening
Organic Letters2007Vol. 9(13), pp. 2541–2544
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Andrey A. Fokin, Ekaterina D. Butova, Lesya V. Chernish, Natalie A. Fokina, Jeremy Dahl, Robert M. K. Carlson, Peter R. Schreiner
Abstract
The transformations of apical mono- and bisacetyl diamondoids to the respective oxetanes and subsequent acid-catalyzed ring opening/dehydration lead to diamondoidyl mono- and bis-1,3-dienes in high preparative yields.
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