Substituted Pyrroles via Olefin Cross-Metathesis
Organic Letters2010Vol. 12(18), pp. 4094–4097
Citations Over TimeTop 10% of 2010 papers
Abstract
Olefin cross-metathesis (CM) provides a short and convenient entry to diverse trans-γ-aminoenones. When exposed to either acid or Heck arylation conditions, these intermediates are converted to mono-, di-, or trisubstituted pyrroles. The value of this chemistry is demonstrated by its application to the tetrasubstituted pyrrole subunit of Atorvastatin.
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