1,1-Carboboration of 1-Alkynes: A Conceptual Alternative to the Hydroboration Reaction
Organic Letters2010Vol. 13(1), pp. 62–65
Citations Over TimeTop 10% of 2010 papers
Abstract
Strongly electrophilic boranes R-B(C(6)F(5))(2) react readily with a variety of 1-alkynes by means of a 1,1-carboboration reaction to yield alkenylborane products, which can subsequently be used as reagents in metal catalyzed cross-coupling reactions.
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