Iodo-cyclizations: Novel Strategy for the Total Syntheses of Polyrhacitide A and epi-Cryptocaryolone
Organic Letters2011Vol. 13(4), pp. 744–747
Citations Over TimeTop 15% of 2011 papers
Abstract
Highly stereoselective total syntheses of polyrhacitide A and epi-cryptocaryolone have been achieved in 11 steps with high overall yield of 24% and 28%, respectively, following a recently developed strategy for the construction of trans-2,6-disubstituted-3,4-dihydropyrans. In this report, the versatility of iodo-cyclization for the total syntheses of polyrhacitide A and epi-cryptocaryolone is demonstrated.
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