Palladium-Catalyzed Denitrogenation Reaction of 1,2,3-Benzotriazin-4(3H)-ones Incorporating Isocyanides
Organic Letters2011Vol. 13(6), pp. 1429–1431
Citations Over TimeTop 10% of 2011 papers
Abstract
1,2,3-Benzotriazin-4(3H)-ones and 1,2,3,4-benzothiatriazine 1,1(2H)-dioxide reacted with isocyanides in the presence of a palladium catalyst to give 3-(imino)isoindolin-1-ones and 3-(imino)thiaisoindoline 1,1-dioxides, respectively, in high yield. An intermediate azapalladacycle was generated through denitrogenation of the triazine moiety, and an isocyanide was incorporated therein.
Related Papers
- → Synthesis and Shuttling Behavior of [2]Rotaxanes with a Pyrrole Moiety(2016)26 cited
- → Preparation of organo palladium sols from palladium complexes in various alcohols(1994)32 cited
- → The constitution of cerium-palladium alloys containing 50–100% palladium(1967)48 cited
- → Allyl(β‐diketonato)palladium(II) complexes as precursors for palladium films(1994)36 cited
- Design, synthesis and evaluation of novel hydroxyethylamine derivatives with nitrogen heterocyclic moiety at N-terminal as BACE1 inhibitors(2010)