Benzotrithiophene - A Planar, Electron-Rich Building Block for Organic Semiconductors
Organic Letters2011Vol. 13(9), pp. 2414–2417
Citations Over TimeTop 10% of 2011 papers
Christian B. Nielsen, Jamie M. Fraser, Bob C. Schroeder, Junping Du, Andrew J. P. White, Weimin Zhang, Iain McCulloch
Abstract
Several functionalized benzo[1,2-b:3,4-b':5,6-d'']trithiophenes have been synthesized and characterized. The fully planar and highly electron-rich material shows great promise as the donor constituent in donor-acceptor type copolymers for use in organic electronics. As a proof of concept, a copolymer with the electron acceptor, 2,1,3-benzothiadiazole, has been prepared. Side-chain modifications have been employed to adjust both the electron-rich character of the monomer and the solubility and processability of the polymer.
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