New Ligands That Promote Cross-Coupling Reactions between Aryl Halides and Unactivated Arenes
Organic Letters2011Vol. 13(14), pp. 3556–3559
Citations Over TimeTop 10% of 2011 papers
Abstract
Several ligands were designed to promote transition-metal-free cross-coupling reactions of aryl halides with benzene derivatives. Among the systems probed, quinoline-1-amino-2-carboxylic acid was found to serve as an excellent catalyst for cross-coupling between aryl halides and unactivated benzene. Reactions using this inexpensive catalytic system displayed a high functional group tolerance as well as excellent chemoselectivities.
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