Rhodium-Catalyzed Selective C–H Activation/Olefination of Phenol Carbamates
Organic Letters2011Vol. 13(12), pp. 3235–3237
Citations Over TimeTop 1% of 2011 papers
Abstract
Rh(III)-catalyzed ortho C-H activation/olefination of phenol carbamates has been developed. High regioselectivity is observed with a range of phenol carbamates enabling efficient coupling with acrylates and styrenes. This reaction exhibits different reactivity as compared to the Pd-catalyzed ortho-arylation reaction of phenol esters and provides a new approach for the synthesis of ortho-substituted phenols.
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