Accelerated Ring-Opening Metathesis Polymerization of a Secondary Amide of 1-Cyclobutene by Hydrogen-Bonding Interaction
Organic Letters2011Vol. 13(15), pp. 3908–3911
Citations Over TimeTop 21% of 2011 papers
Abstract
A hydrogen-bond-assisted model is proposed for ring-opening metathesis polymerization (ROMP) of a secondary amide of 1-cyclobutene, resulting in the fastest reaction rate in a nonpolar solvent, toluene. This new model was supported by the investigation on how the solvent effect affected the NMR spectra, ROMP kinetic studies, and the copolymerization of monomers 1 and 2.
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