Nickel-Catalyzed Amination of Aryl Phosphates through Cleaving Aryl C–O Bonds
Organic Letters2011Vol. 13(14), pp. 3750–3753
Citations Over TimeTop 10% of 2011 papers
Abstract
The amination of triaryl phosphates was achieved using a Ni(II)-(σ-Aryl) complex/NHC catalyst system in dioxane at 110 °C in the presence of NaH as base. Electron-neutral, -rich, and -deficient triaryl phosphates were coupled with a wider range of amine partners including cyclic and acyclic secondary amines, aliphatic primary amines, and anilines in good to excellent yields.
Related Papers
- → Recent advances in transition metal-catalyzed sp3C–H amination adjacent to double bonds and carbonyl groups(2011)467 cited
- → A review on the effect of amination pretreatment for the selective separation of CO2(2015)49 cited
- → Advances in the Direct Amination of Azole C-H Bonds(2011)26 cited
- → Recent Progress in Amination Enabled by Transition-Metal-Free C(sp2)–O/C(sp2)–S Bond Cleavage Strategy(2021)3 cited
- → Catalytic CH Amination with Nitrenes(2007)5 cited